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Comparison of the photochemical and thermal rearrangement reaction of endoperoxides

✍ Scribed by R. Schmidt; H.-D. Brauer

Publisher
Elsevier Science
Year
1986
Weight
864 KB
Volume
34
Category
Article
ISSN
0047-2670

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## Abstract The chemistry of two bicyclic endoperoxides, obtained by photooxygenation of 2,3‐benzotropone (=5__H__‐benzocyclohepten‐5‐one; **5**) and of its ethyl carboxylate derivative **15**, was investigated with the aim of synthesizing the respective benzotropolone derivatives. The reaction of