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Comparison of the photocatalytic metatheses of terminal and internal olefins: metathesis of 2-octene

✍ Scribed by B. Zümreoǧlu-Karan; Y. İmamoǧlu


Book ID
103693667
Publisher
Elsevier Science
Year
1991
Weight
455 KB
Volume
65
Category
Article
ISSN
0304-5102

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The W(O-2,6-C 6 H 3 X 2 ) 2 Cl 4 /Bu 4 Sn catalytic systems (X Ph, F, Cl, Br) have a high activity for the metathesis of terminal alkenes and a high selectivity towards primary metathesis products. Tungsten(VI) alkoxide complexes are not nearly as active as the tungsten(VI) aryloxide complexes. Br˘n