Comparison of the electrochemical reductions of Ru(II) complexes of dipyrido[3,2-a:2′,3′-c]phenazine and 10,12-dimethylpteridino[6,7-f][1,10]phenanthroline-11,13(10H,12H)-dione (an alloxazine analog) in aprotic and mixed aprotic/aqueous media

Synthesis, Characterization, and DNA-Bin

Synthesis, Characterization, and DNA-Binding Properties of the Chiral Ruthenium(II) Complexes Δ- and Λ-[Ru(bpy)2(dmppd)]2+ (dmppd = 10,12-Dimethylpteridino[6,7-f] [1,10]phenanthroline-11,13(10H,12H)-dione; bpy = 2,2′-Bipyridine)

✍ Feng Gao; Hui Chao; Feng Zhou; Lian-Cai Xu; Kang-Cheng Zheng; Liang-Nian Ji 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 German ⚖ 255 KB 👁 1 views

## Two novel chiral ruthenium(II) complexes, D-[Ru(bpy 10,12-dimethylpteridino[6,7-f] [1,10] phenanthroline-11,13(10H,12H)-dione, bpy = 2,2'-bipyridine), were synthesized and characterized by elemental analysis, 1 H-NMR and ES-MS. The DNA-binding behaviors of both complexes were studied by UV/VIS