Shift of the rate-determining step in a
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M. Enyo
📂
Article
📅
1975
🏛
John Wiley and Sons
🌐
English
⚖ 355 KB
## Abstract A consecutive single‐route reaction is considered. When two (groups of) steps compete in controlling the overall reaction rate, there exists a general rule that the earlier step in the flow of the overall reaction tends to be rate‐determining with the increase of the reaction affinity.