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Comparison of reduced and oxidized yeast iso-1-cytochrome c using proton paramagnetic shifts

✍ Scribed by Gao, Yuan; Boyd, Jonathan; Pielak, Gary J.; Williams, Robert J. P.


Book ID
127237932
Publisher
American Chemical Society
Year
1991
Tongue
English
Weight
786 KB
Volume
30
Category
Article
ISSN
0006-2960

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Amide proton exchange rates of oxidized
✍ Jennifer L. Marmorino; Douglas S. Auld; Stephen F. Betz; Donald F. Doyle; Gregor πŸ“‚ Article πŸ“… 1993 πŸ› Cold Spring Harbor Laboratory Press 🌐 English βš– 979 KB

## Abstract Proton NMR spectroscopy was used to determine the rate constant, __k~obs~__, for exchange of labile protons in both oxidized (Fe(III)) and reduced (Fe(II)) iso‐1‐cytochrome __c.__ We find that slowly exchanging backbone amide protons tend to lack solvent‐accessible surface area, possess