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Hydrogen Exchange Behavior of [ U - 15 N]-Labeled Oxidized and Reduced Iso-1-cytochrome c †

✍ Scribed by Baxter, Susan M.; Fetrow, Jacquelyn S.


Book ID
126017818
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
124 KB
Volume
38
Category
Article
ISSN
0006-2960

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Amide proton exchange rates of oxidized
✍ Jennifer L. Marmorino; Douglas S. Auld; Stephen F. Betz; Donald F. Doyle; Gregor 📂 Article 📅 1993 🏛 Cold Spring Harbor Laboratory Press 🌐 English ⚖ 979 KB

## Abstract Proton NMR spectroscopy was used to determine the rate constant, __k~obs~__, for exchange of labile protons in both oxidized (Fe(III)) and reduced (Fe(II)) iso‐1‐cytochrome __c.__ We find that slowly exchanging backbone amide protons tend to lack solvent‐accessible surface area, possess