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Comparison of Physical and Photophysical Properties of Monometallic and Bimetallic Ruthenium(II) Complexes Containing Structurally Altered Diimine Ligands

✍ Scribed by Macatangay, Ariel; Zheng, Greg Y.; Rillema, D. Paul; Jackman, Donald C.; Merkert, Jon W.

Book ID: 126807315
Publisher: American Chemical Society
Year: 1996
Tongue: English
Weight: 211 KB
Volume: 35
Category: Article
ISSN: 0020-1669
DOI: 10.1021/ic9513447

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## Abstract The synthesis of a number of new 2,2′‐bipyridine ligands functionalized with bulky amino side groups is reported. Three homoleptic polypyridyl ruthenium (II) complexes, [Ru(L)~3~]^2+^ 2(PF~6~^−^), where L is 4,4′‐dioctylaminomethyl‐2,2′‐bipyridine (Ru4a), 4,4′‐didodecylaminomethyl‐2,2′‐