Physical, photophysical and structural properties of ruthenium(ii) complexes containing a tetradentate bipyridine ligand
β Scribed by Kirgan, R. A.; Witek, P. A.; Moore, C.; Rillema, D. P.
- Book ID
- 120060873
- Publisher
- Royal Society of Chemistry
- Year
- 2008
- Tongue
- English
- Weight
- 488 KB
- Volume
- 24
- Category
- Article
- ISSN
- 1477-9226
- DOI
- 10.1039/B800531A
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The temperature dependence of the emission lifetime of the series of complexes Ru(bpy),(4,4'-dpb): ? (bpy = 2,2'-bipyridine, 4,4'-dpb = 4,4'-diphenyL2,2'-bipyridine) has been studied in propionitrile/butyronitrile (4:5 u/u) solutions in the range 90-293 K. The obtained photophysical parameters show
We have synthesized a new type of tris-2,2'-bipyridine ligand of 7 and 8 do not interact appreciably, as is evident from their with 4,4'-and 6,6'-disubstituted 2,2'-bipyridine (bpy) units. electrochemical and photophysical data. The lifetime of the The terminal 4,4'-disubstituted 2,2'-bipyridine moi