✦ LIBER ✦

Comparison of He I and He II photoelectron spectra of phosphoryl chloride

✍ Scribed by T.H. Gan; J. Barrie Peel; Gary D. Willett

Publisher: Elsevier Science
Year: 1977
Tongue: English
Weight: 325 KB
Volume: 48
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(77)85076-8

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✦ Synopsis

The He I and He II photoelectron spectra of phosphoryl chloride, POCI a, have been measured. Because of :he relative intensity loss for He !! radiation experienced by ion states formed by ionization of localized C1 non-bonding e! ectrons, the two spectra show considerable differences. By combining NEVE molecular orbital compositions with theoretical atomic cross-section data, the correlation of calculated and observed intensity variations confirm the assignment of th~ POC I~ ion states.

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