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Comparison of different 6-tert-butyldimethyl-silylated cyclodextrins as chiral stationary phases in GC

✍ Scribed by Birgit Maas; Armin Dietrich; Armin Mosandl

Publisher: John Wiley and Sons
Year: 1996
Tongue: English
Weight: 713 KB
Volume: 8
Category: Article
ISSN: 1040-7685
DOI: 10.1002/(sici)1520-667x(1996)8:1<47::aid-mcs7>3.0.co;2-8

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✦ Synopsis

Separation factors and thermodynamic data for the separation of various chiral analytes on different 6-TBDMS-derivatized y( p )-cyclodextrin-phases were collected and discussed. Modifying the alkyl chain length of the substituents in position 2, and 3 of the cyclodextrin molecule or changing from p to y-CD affects the separation properties extremely, whereas changing the chain length of acyl groups in position 2 and 3 hardly influences enantioselectivity.

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