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Comparison between the thermal and photochemical 1,3-cycloaddition reactions of ethyl 2-methyl-3-phenylglycidate with benzaldehyde. Thermal fission of a carbonyl ylide

โœ Scribed by Kagan, Jacques; Firth, Bruce E.


Book ID
125999733
Publisher
American Chemical Society
Year
1974
Tongue
English
Weight
406 KB
Volume
39
Category
Article
ISSN
0022-3263

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The photochemical 1,3-cycloaddition of c
โœ J. Kagan; J.T. Przybytek; B.E. Firth; S.P. Singh ๐Ÿ“‚ Article ๐Ÿ“… 1972 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 203 KB

reoeived in UX for publication 13 IVovambsr 1972) When a benzene solution of either cis &-c) or trans 2-methyl-3-phenylglycidate 2-g) was irradiated in benzene under N 2 at 254 nm for 48 hrs., about 20% conversion to a complex mixture was observed. Silica gel chromatography afforded only one crystal