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Comparing atmospheric [HO 2 ]/[OH] to modeled [HO 2 ]/[OH]: Identifying discrepancies with reaction rates

✍ Scribed by Lanzendorf, E. J.; Hanisco, T. F.; Wennberg, P. O.; Cohen, R. C.; Stimpfle, R. M.; Anderson, J. G.

Book ID
119655307
Publisher
American Geophysical Union
Year
2001
Tongue
English
Weight
542 KB
Volume
28
Category
Article
ISSN
1944-8007

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The rate of the reaction (1) NO + HOz + OH + NO2 was determined in an isothermal discharge flow reactor with a combined ESR-LMR detection under pseudo-first-order conditions in HOz. The rate constant was identical in experiments with two different HOn sources: F + H202 and H + 0 2 + M. The absolute