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Comparative trapping kinetics of silylene. I. Silylene reactions with 1,3-butadiene and acetylene and with 1,3-butadiene and methanol

โœ Scribed by Rogers, D. S.; O'Neal, H. E.; Ring, M. A.

Book ID
127112859
Publisher
American Chemical Society
Year
1986
Tongue
English
Weight
822 KB
Volume
5
Category
Article
ISSN
0276-7333

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Di-tert-butylsilylene, generated by photolysis of hexa-tert-gives the corresponding alkynylsilirenes 14 and 15, respectively. Photolysis of 1 or 2 in the presence of (Me 3 Si-butylcyclotrisilane 1 or 1,1-di-tert-butyl-trans-2,3-dimethylsilirane (2), reacts with the 1,3-diyne (tBu-CฯตC-) 2 9 to CฯตC-)