Comparative Study of Various Mechanisms for Metallocene-Catalyzed α-Olefin Polymerization
✍ Scribed by Silanes, Iñaki; Ugalde, Jesus M.
- Book ID
- 126423501
- Publisher
- American Chemical Society
- Year
- 2005
- Tongue
- English
- Weight
- 367 KB
- Volume
- 24
- Category
- Article
- ISSN
- 0276-7333
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📜 SIMILAR VOLUMES
DFT (density-functional theory) calculations were performed to investigate the thermodynamics of formation of Olefin Separated Ion Pairs (OSIP) Cp2MtCH~/C2H4/Cl2AI[O(A1Me3)AlHMe]; (Cp = q5-C5H5, Mt = Ti, Zr, Me = CH3) from ethylene and Cp2MtMe \* C12AI[O(AlMe3)A1HMe]2, a model of adduct produced by
## Abstract The replacement of MAO by different aluminum alkyls in the polymerization of higher __α__‐olefins catalyzed by __rac__‐EtInd~2~ZrCl~2~ and __rac__‐(CH~3~)~2~CInd~2~ZrCl~2~ and in the syndiospecific polymerization of styrene with CpTiCl~3~ as a catalyst was studied. An activating effect