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Toward Quantitative Prediction of Stereospecificity of Metallocene-Based Catalysts for α-Olefin Polymerization

✍ Scribed by Angermund, Klaus; Fink, Gerhard; Jensen, Vidar R.; Kleinschmidt, Ralph

Book ID: 125887237
Publisher: American Chemical Society
Year: 2000
Tongue: English
Weight: 292 KB
Volume: 100
Category: Article
ISSN: 0009-2665
DOI: 10.1021/cr990373m

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## Abstract Four supported metallocene catalysts were synthesized directly on silica [Si(CpZrCp), Si(CpZrInd), Si(IndZrCp), and Si(IndZrInd)]. The first ligand was chemically tethered to silica (internal ligand) while the second was free from silica (external ligand). The polymerization of ethylene