Comparative Study of Methods for the Identification of Cis- and Trans-Isomers of the Octahedral Complex Ion [CoEn2(NCS)2]+
β Scribed by J. J. A. Hartmann; G. P. van der Kelen
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 2010
- Weight
- 525 KB
- Volume
- 68
- Category
- Article
- ISSN
- 0037-9646
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
Complete optimization of the molecular geometry of NzF2 confirmed the two previously assumed activated complexes (AC's) for the title reaction. The contributions of both AC's were precisely weighed up in terms of the activated-complex theory. The possibdity of an autocatalysed chain mechanism is dis
The OH stretching wavenumbers of the cis and trans conformers of 2-halophenols were studied in the gas phase by using coherent anti-Stokes Raman spectroscopy and quantum chemical calculations. The wavenumber di β erences between the two isomers of 2-Γuoro-, 2-chloro-and 2-bromophenol were found to be
## Abstract Eight hypothetical persulfurane molecules of the type X~2~SY~4~ (X, Y = H, F, Me) have been studied by ab initio MO calculations at the G3(MP2) level of theory. Depending on the substituents either the __cis__ or the __trans__ isomers of these octahedral molecules are most stable. While