2 ) 3 (trans isomer only). The 183 W chemical shift (obtained by indirect detection using 31 P) is found to be related to the PR 3 ligand parameters Ξ½ and ΞΈ (Tolman electronic factor and cone angle, respectively) for the cis isomers and to Ξ½ (but only poorly to ΞΈ ) for the trans isomers. The 183 W-3
Vibrational spectra of the cis and trans isomers of the Mo(CO)4(PPh3)2 complex
β Scribed by J. Shamir; A. Givan; M. Ardon; G. Ashkenazi
- Publisher
- John Wiley and Sons
- Year
- 1993
- Tongue
- English
- Weight
- 440 KB
- Volume
- 24
- Category
- Article
- ISSN
- 0377-0486
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π SIMILAR VOLUMES
## Abstract The reaction of [Mo(CO)~3~(MeCN)~3~] with K~4~Pb~9~ in the presence of 2.2.2βcryptand (2.2.2βcrypt) has been investigated. The transition metal complex [K(2.2.2βcrypt)]~4~[(Ξ·^5^__β__Pb~9~)Mo(CO)~3~] (1), which contains a Pb~9~^4β^ Zintl anion coordinated by Mo in an Ξ·^5^βfashion, is iso
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v