Comparative stereochemical studies of Ph3SnL complexes (L = 1-carbodithioato vs. 1-carbothioato ligand). Crystal structures of [Ph3Sn(S.CS.N(CH2)5] and [Ph3Sn(S.CO.N(CH2)4O)]
✍ Scribed by Shubhra Chandra; Bruce D. James; Robert J. Magee; Wyona C. Patalinghug; Brian W. Skelton; Allan H. White
- Publisher
- Elsevier Science
- Year
- 1988
- Tongue
- English
- Weight
- 387 KB
- Volume
- 346
- Category
- Article
- ISSN
- 0022-328X
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## Abstract A series of mono‐ and disubstituted diiron complexes [(μ‐pdt)Fe~2~(CO)~5~L] [pdt = 1,3‐propanedithiolato; L = PMe~3~ (2), PMe~2~Ph (3PPh~3~ (4), P(OEt)~3~ (5)] and [(μ‐pdt)Fe~2~(CO)~4~L~2~] [L = PMe~2~Ph (6), PPh~3~ (7), P(OEt)~3~ (8)] were prepared as Fe‐only hydrogenase‐active‐site mo
In this study are reported the syntheses of three bis(diarylhydrazonecarbonyl 6), and 2-C 4 H 3 S ( 7)], obtained by condensation of corresponding hydrazones with carbon suboxide, C 3 O 2 . The solid-state self-assembly of these carbonyl derivatives, giving rise to polymeric and dimeric networks, is