Comparative Effects of Conjugated and Deconjugated Isomeric Enones on the Transannular Diels−Alder Reaction
✍ Scribed by Caussanel, Franck; Deslongchamps, Pierre; Dory, Yves L.
- Book ID
- 125898371
- Publisher
- American Chemical Society
- Year
- 2003
- Tongue
- English
- Weight
- 150 KB
- Volume
- 5
- Category
- Article
- ISSN
- 1523-7060
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📜 SIMILAR VOLUMES
Hetero Diels-Alder reactions / Enamino ketones 1 High-pressure reactions / Pyrans The hetero Diels-Alder reaction of enamino ketone 1 with the vinyl ethers 7-11 leading to the dihydropyrans 12a-e and 13ae is studied in dichloromethane under high pressures up to 7 kbar. The kinetics is measured by o
A sterically unbiased macrocyclic probe has been used to study the Diels-Alder reaction mechanism of enal dienophiles. All the results, theoretical as well as kinetical, converge to the conclusion that a virtually non-concerted zwitterioulc mechanism is possible for certain cases of Lewis acid catal