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Communications-The Oxidation of Epoxides by Dimethyl Sulfoxide. A simple Synthesis of α-Hydroxy Ketones.

✍ Scribed by Cohen, Theodore; Tsuji, Tadakazu


Book ID
119945118
Publisher
American Chemical Society
Year
1961
Tongue
English
Weight
123 KB
Volume
26
Category
Article
ISSN
0022-3263

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A kinetic study of the oxidation of α-hy
✍ R. Natarajan; N. Venkatasubramanian 📂 Article 📅 1976 🏛 John Wiley and Sons 🌐 English ⚖ 346 KB

## Abstract The oxidation of α‐hydroxy acids and α‐hydroxy ketones by Br(V) follows the rate‐law However, the former reaction exhibits a second‐order dependence on hydrogen ion concentration while the latter reaction has a third‐order dependence. A mechanism involving a slow formation of a bromate