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Comment on theories of interfacial tension of polymeric interfaces

โœ Scribed by Noolandi, Jaan ;Chen, Zheng Yu

Publisher
Wiley (John Wiley & Sons)
Year
1992
Weight
147 KB
Volume
1
Category
Article
ISSN
1018-5054

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โœฆ Synopsis

Abstract

A simple scaling argument is shown to give the correction to the interfacial tension of two infiniteโ€molecularโ€weight immiscible homopolymers arising from the translational entropy of finiteโ€sized chains. It is suggested that the qualitative nature of the Floryโ€Huggins model, as shown by Binder and coworkers, precludes meaningful detailed comparison of experimental data with current theoretical expressions for the interfacial tension.

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