A new model is proposed for the calculation of the interfacial tension between an organic solvent and concentrated aqueous solutions of electrolytes. The interfacial tension is derived from the isothermal Gibbs equation. The increase or decrease of interfacial tension with concentrations are modeled
A Linear Gradient Theory Model for Calculating Interfacial Tensions of Mixtures
β Scribed by You-Xiang Zuo; Erling H. Stenby
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 181 KB
- Volume
- 182
- Category
- Article
- ISSN
- 0021-9797
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β¦ Synopsis
made in combining the Helmholtz energy of the bulk phases In this research work, we assumed that the densities of each with the gradient theory (GT) of the interface. The GT has component in a mixture are linearly distributed across the interbeen successfully used for estimating interfacial properties face between the coexisting vapor and liquid phases, and we develof pure fluids and mixtures ; oped a linear gradient theory model for computing interfacial ten- ; Gupta and sions of mixtures, especially mixtures containing supercritical
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