Comment on the “absolute reaction rate theory”
✍ Scribed by James D. Macomber; Carolyn Colvin
- Publisher
- John Wiley and Sons
- Year
- 1969
- Tongue
- English
- Weight
- 133 KB
- Volume
- 1
- Category
- Article
- ISSN
- 0538-8066
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Claims have recently been made that absolute rate constants for chain propagation of the unassociated active centers can be made in systems where a high degree of association is present. Anionic polymerization of styrene in nonpolar solvents with lithium as counterion is a typical case. The conditio
## Abstract Review: 153 refs.
In the case of catalytic dehydrogenation of cyclohexane, the linear relation between reaction rate and affinity holds at an appreciable distance away from equilibrium on both sides. In fact, in order to explain this observation, it is necessary to invoke a high value of three for the stoichiometric