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Comment on hydrocarbon diffusivity in zeolites

✍ Scribed by Jürgen Caro; Martin Bülow; Jörg Kärger

Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
138 KB
Volume
40
Category
Article
ISSN
0009-2509

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Deprotonation of hydrocarbon radical cat
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Neutral radicals are observed at 77 K following radiolysis of cycloheptatriene and cyclohexane adsorbed on ZSM-5 zeolites. The mechanism of radical formation is assigned to proton transfer from the sorbate radical cations to the zeolite lattice. In the case of cycloheptatriene, the ratio C,H;/C,H,+'