Combined use of X-ray photoelectron and Mössbauer spectroscopic techniques in the analytical characterization of iron oxidation state in amphibole asbestos
✍ Scribed by Marzia Fantauzzi; Alessandro Pacella; Davide Atzei; Antonio Gianfagna; Giovanni B. Andreozzi; Antonella Rossi
- Publisher
- Springer
- Year
- 2010
- Tongue
- English
- Weight
- 353 KB
- Volume
- 396
- Category
- Article
- ISSN
- 1618-2650
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A series of bis(polypyrazolylborato)iron(II) complexes (with Tp 3CF3 , Tp 4Me , Tp 4Br , and pzTp 4Me ) has been prepared and characterised by 57 Fe Mo ¨ssbauer spectroscopy. In addition, the Tp 3CF3 has been studied and compared with Tp 3CH3 by X-ray absorption investigation. The X-ray crystal stru
The Hartree-Fock method is used to calculate the KG trawition energy for a number of configurations of different Fe ions. Experimental X-ray emission G shifts are combined with Massbauer isomer shifts to estimate the effective mtiguratioae of the iron ion.