Combinations of alkyl radicals with alkyl and substituted allyl radicals
✍ Scribed by Seres, László ;Görgényi, Miklós ;Körtvélyesi, Tamás ;Nacsa, Ágnes
- Book ID
- 112706146
- Publisher
- Springer
- Year
- 1992
- Tongue
- English
- Weight
- 160 KB
- Volume
- 48
- Category
- Article
- ISSN
- 0133-1736
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📜 SIMILAR VOLUMES
New experimental results pertaining to p-group (ML3) interaction in radicals of type R2C-CH2ML3 have led Griller and Ingold(1) to conclude that the theory involving 0-n hyperconjugation, invoked by Lyons and Symons(2) to explain the conformation exhibited by certain radicals of this type, must be re
## Abstract The Hg(6^3^__P__~1~) photosensitized decompositions of 3‐methyl‐1‐butene, 2‐methyl‐2‐butene, 3,3‐dimethyl‐1‐butene, and 2,3‐dimethyl‐1‐butene have been used to generate 1‐methylallyl, 1,2‐dimethylallyl, 1,1‐dimethylallyl, and 1,1,2‐trimethylallyl radicals in the gas phase at 24 ± 1°C. F
pretation is supported by the significantly lengthened Si-C bonds (I99 pm compared with 187 pm for the single bond) and the expanded angle at the tertiary C atoms (C-C-C between 104.2 and 106.5", Si-C-C between 110.9 and 114.8"). The Si-Si distance in 1 corresponds to a Pauling bond order of 0.45 an