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Combinations of alkyl radicals with alkyl and substituted allyl radicals

✍ Scribed by Seres, László ;Görgényi, Miklós ;Körtvélyesi, Tamás ;Nacsa, Ágnes


Book ID
112706146
Publisher
Springer
Year
1992
Tongue
English
Weight
160 KB
Volume
48
Category
Article
ISSN
0133-1736

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📜 SIMILAR VOLUMES


Conformation and hyperconjugation in β-s
✍ M.C.R. Symons 📂 Article 📅 1975 🏛 Elsevier Science 🌐 French ⚖ 226 KB

New experimental results pertaining to p-group (ML3) interaction in radicals of type R2C-CH2ML3 have led Griller and Ingold(1) to conclude that the theory involving 0-n hyperconjugation, invoked by Lyons and Symons(2) to explain the conformation exhibited by certain radicals of this type, must be re

Reactions of unsymmetrically substituted
✍ D. C. Montague 📂 Article 📅 1973 🏛 John Wiley and Sons 🌐 English ⚖ 539 KB

## Abstract The Hg(6^3^__P__~1~) photosensitized decompositions of 3‐methyl‐1‐butene, 2‐methyl‐2‐butene, 3,3‐dimethyl‐1‐butene, and 2,3‐dimethyl‐1‐butene have been used to generate 1‐methylallyl, 1,2‐dimethylallyl, 1,1‐dimethylallyl, and 1,1,2‐trimethylallyl radicals in the gas phase at 24 ± 1°C. F

Metathesis of Alkyl Radicals and Alkenes
✍ Priv.-Doz. Dr. Jürgen O. Metzger 📂 Article 📅 1986 🏛 John Wiley and Sons 🌐 English ⚖ 236 KB 👁 2 views

pretation is supported by the significantly lengthened Si-C bonds (I99 pm compared with 187 pm for the single bond) and the expanded angle at the tertiary C atoms (C-C-C between 104.2 and 106.5", Si-C-C between 110.9 and 114.8"). The Si-Si distance in 1 corresponds to a Pauling bond order of 0.45 an