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Combination of ionic and metal-olefin bonds in crystalline copper(I) π-complexes

✍ Scribed by V. V. Olijnik; E. A. Goreshnik


Book ID
110563577
Publisher
SP MAIK Nauka/Interperiodica
Year
1994
Tongue
English
Weight
531 KB
Volume
35
Category
Article
ISSN
0022-4766

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Olefin-Metal π-Interactions of Mercury a
✍ Markus Enders; Gunter Ludwig; Hans Pritzkow 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 234 KB 👁 1 views

## Mercury / Zinc / N ligands / π interactions The donor-functionalised cyclopentadiene derivative 1 acts as a neutral chelate ligand and forms the zinc and mercury complexes 2 and 3 upon treatment with HgCl 2 or ZnCl 2 . Due to the predefined geometry of 1, the MCl 2 moieties are found in close p