✦ LIBER ✦
Olefin-Metal π-Interactions of Mercury and Zinc Ions in Complexes of Neutral Quinolylcyclopentadiene Derivatives
✍ Scribed by Markus Enders; Gunter Ludwig; Hans Pritzkow
- Publisher
- John Wiley and Sons
- Year
- 2002
- Tongue
- English
- Weight
- 234 KB
- Volume
- 2002
- Category
- Article
- ISSN
- 1434-1948
No coin nor oath required. For personal study only.
✦ Synopsis
Mercury / Zinc / N ligands / π interactions
The donor-functionalised cyclopentadiene derivative 1 acts as a neutral chelate ligand and forms the zinc and mercury complexes 2 and 3 upon treatment with HgCl 2 or ZnCl 2 . Due to the predefined geometry of 1, the MCl 2 moieties are found in close proximity to the π-system of the cyclopentadiene. In the mercury compound 3 there is some evidence for a bond