Columnar Organization in Mesogenic cis - and trans -[MX 2 (C⋮NR) 2 ] Complexes (M = Pd, Pt)
✍ Scribed by Coco, Silverio; Díez-Expósito, Fátima; Espinet, Pablo; Fernández-Mayordomo, César; Martín-Álvarez, José M.; Levelut, A. Marie
- Book ID
- 120169253
- Publisher
- American Chemical Society
- Year
- 1998
- Tongue
- English
- Weight
- 83 KB
- Volume
- 10
- Category
- Article
- ISSN
- 0897-4756
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It is shown that the ligand 2,ll-bis(diphenylphosphinomethyl)benzo[c]phenanthrene (1) reacts with nickel(II), palladium(I1) and platinum(l1) substrates giving either exclusively, or predominantly, mononuclear complexes of the type trans-[MXz (l)] in which the organic ligand spans trans-positions. It
## Abstract Complexes [MX~2~(1)] (M = Ni, Pd and Pt; X=Cl and NCS; 1 = 2,11‐bis(dialkyl‐[or diaryl]phosphinomethyl)benzo[__c__]phenanthrene; alkyl = cyclohexyl __t__‐butyl; aryl = __m__‐tolyl, __p__‐anisyl and __m__‐CF~3~ C~6~H~4~) have been synthesized. An NMR. study of the t‐butyl complexes prov
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