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13C and 195Pt NMR of para-substituted N,N-dialkyl-N′-benzoylthioureas and their cis-[ML2] complexes, M = Pd(II) and Pt(II)

✍ Scribed by Klaus R. Koch; Mangaka C. Matoetoe

Publisher
John Wiley and Sons
Year
1991
Tongue
English
Weight
221 KB
Volume
29
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

A series of neutral cis‐[ML~2~] complexes, where M = Pd(II) and Pt(II) and L = para‐substituted N,N‐dialkyl‐N′‐benzoyl‐thio‐urea anion, were examined by means of ^13^C and ^195^Pt NMR. Unambiguous assignment of the thiocarbonyl carbon atom in these complexes was achieved with ^13^C isotopic enrichment and the resolved ^n^J(^195^Pt, ^13^C) coupling satellites.

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