Synthesis of the C6๎ธC16 polyene fragment
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Eckhard Claus; Markus Kalesse
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Article
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1999
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Elsevier Science
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French
โ 188 KB
The Pd-catalyzed synthesis of the polyene fragment of ratjadone is described. This strategy employs the Stille-coupling for the coupling of the tetrahydropyran subunit and the Suzuki coupling for attaching the unsaturated lactone to the polyene chain.