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Collisional relaxation in CO2 between 180 K and 400 K measured by the spectrophone method

✍ Scribed by F. Lepoutre; G. Louis; H. Manceau

Publisher: Elsevier Science
Year: 1977
Tongue: English
Weight: 473 KB
Volume: 48
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(77)85082-3

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✦ Synopsis

The spcctrophonc method IS uc.cd to study cxpcrtmcntally the dcaztivntlon of the fust level of the asymmetrrc strctch:ns mode between 193 K and 408 K. InformatIon is Gmultancously obtamed on the V-V cxch.mges between the IcveI (OOo I) and the first levclc of the symmctruz strctcbing mode (s) and the bcndmg mode (h) and on the V-1 exchange bctwccn thcsc modcs (b), (3 and the translation rotation degrees of freedom. The cxperlmental results are compared wtth those from tkc iitcrature. A discussion follows which proposes scvera) explanations concerntng the theoretrca~ mterprctation of the resuk

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