Collisional-radiative simulations of a radiative pumping experiment
โ Scribed by C.C. Smith; D.J. Hoarty; S. Mouncey
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 623 KB
- Volume
- 54
- Category
- Article
- ISSN
- 0022-4073
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The emission following single-photon excitation of the first excited singlet state of acetone was studied. Stis muhi-exponential and extremely prm sensitive. vibrationally hot triplet molecules above the singlet origin decay significantly faster than those below. At 91.5 f 0.5 kcal/mole above the gr
PH (b 'C? has been obtained in the vacmzm ultravioiolet flash photolysis of PH3 and detected by the 697.3 nm emission due to the forbidden transition PH (b 'Z \* -+ X 3Z-). Rate coefficients for mdiitive and collisional deactivatioa have been determined by time resolved measurements. A radiative Iif