Collisional energy transfer, intramolecular vibrational relaxation and unimolecular reactions
β Scribed by Smith, Ian W. M.
- Book ID
- 120184183
- Publisher
- Royal Society of Chemistry
- Year
- 1997
- Tongue
- English
- Weight
- 347 KB
- Volume
- 93
- Category
- Article
- ISSN
- 0956-5000
- DOI
- 10.1039/A704144F
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π SIMILAR VOLUMES
Using the exponcntll model for the collisional transition probability, it is sholtn that relawtion of average internal ensrg? is d medwe of bullxverage energy transfer K&3). This is a macroscopic property which is a complicated function of both time .md initial excitation .md 1s only distantly relat
For simple models of the relaxation of highly vibrationally excited molecules the average energy transferred per collision <At} i for molecules with initial energy e, is a significant quantity. For more realistic models (Ae)i is generalized to a quantity [Aqe], which is not strictly an average. We d