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Collisional energy transfer, intramolecular vibrational relaxation and unimolecular reactions

✍ Scribed by Smith, Ian W. M.


Book ID
120184183
Publisher
Royal Society of Chemistry
Year
1997
Tongue
English
Weight
347 KB
Volume
93
Category
Article
ISSN
0956-5000

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πŸ“œ SIMILAR VOLUMES


Relaxation of internal energy and collis
✍ Wendell Forst πŸ“‚ Article πŸ“… 1983 πŸ› Elsevier Science 🌐 English βš– 334 KB

Using the exponcntll model for the collisional transition probability, it is sholtn that relawtion of average internal ensrg? is d medwe of bullxverage energy transfer K&3). This is a macroscopic property which is a complicated function of both time .md initial excitation .md 1s only distantly relat

Sum rules in the theory of vibrational r
✍ Neil Snider πŸ“‚ Article πŸ“… 1989 πŸ› Elsevier Science 🌐 English βš– 301 KB

For simple models of the relaxation of highly vibrationally excited molecules the average energy transferred per collision <At} i for molecules with initial energy e, is a significant quantity. For more realistic models (Ae)i is generalized to a quantity [Aqe], which is not strictly an average. We d