Collisional Dissociation of CH3O2+
β Scribed by H. Villinger; A. Saxer; R. Richter; W. Lindinger
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- English
- Weight
- 309 KB
- Volume
- 96
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
The co~sion-educed breakup of CH30; ions, produced in various binary ion-neutral reactions, was investigated in a drift experiment in the energy range from 0.2 to 1.2 eV_ The products observed were HCO* (50%) and HaO* (SO%), tidependent of the coJ.Iision energy inducing the breakup. The energy barrier for the breahaxp is 22 t 6 kcal/moIe_
π SIMILAR VOLUMES
Methylperoxy radicals were generated by the flash photolysis of azomethane-oxygen mixtures. The observed broadband spectrum of the CH302 radical is similar, but not identical to those reported previously. The CH:302 decay followed second-order kinetics a t high CH:jOz concentrations with k4, = (2.5