𝔖 Bobbio Scriptorium
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Collisional Dissociation of CH3O2+

✍ Scribed by H. Villinger; A. Saxer; R. Richter; W. Lindinger


Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
309 KB
Volume
96
Category
Article
ISSN
0009-2614

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✦ Synopsis


The co~sion-educed breakup of CH30; ions, produced in various binary ion-neutral reactions, was investigated in a drift experiment in the energy range from 0.2 to 1.2 eV_ The products observed were HCO* (50%) and HaO* (SO%), tidependent of the coJ.Iision energy inducing the breakup. The energy barrier for the breahaxp is 22 t 6 kcal/moIe_


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Kinetic flash spectroscopic study of the
✍ Charles S. Kan; Robert D. McQuigg; Michael R. Whitbeck; Jack G. Calvert πŸ“‚ Article πŸ“… 1979 πŸ› John Wiley and Sons 🌐 English βš– 676 KB

Methylperoxy radicals were generated by the flash photolysis of azomethane-oxygen mixtures. The observed broadband spectrum of the CH302 radical is similar, but not identical to those reported previously. The CH:302 decay followed second-order kinetics a t high CH:jOz concentrations with k4, = (2.5