Collisional deactivation of vibrationally excited triplet molecules of fluorenone
โ Scribed by G. A. Zalesskaya; A. E. Gololobov; D. L. Yakovlev; V. T. Pavlova
- Publisher
- Springer US
- Year
- 1991
- Tongue
- English
- Weight
- 455 KB
- Volume
- 55
- Category
- Article
- ISSN
- 0021-9037
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Energy removed from highly vlbratlonally excited polyatomic molecutes by polyatomic co&ion partners decreases with increasmg number of atoms in the hot molecule. The trend is qualitatively predicted by two quasi-statistical modek of energy transfer, and calculations of energy removal by the transitt
The W exchange rate for thr Nz-1110 system is determined usmg a hard-core repuist\c patcntial. It is found that the' rapid drzxriration rate zmses from near-resonant VR exchanges in\ol;ing non-dipole ch;~nges in the rot.ttionaI <tdteS I'urIhermore, a chssicai-path approximation is used and the resul