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Collinear quantum mechanical probabilities for the I + HI → IH + I reaction using hyperspherical coordinates

✍ Scribed by Jack A. Kaye; Aron K. Uppermann

Publisher
Elsevier Science
Year
1981
Tongue
English
Weight
558 KB
Volume
77
Category
Article
ISSN
0009-2614

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Collinear quantum mechanical probabiliti
Collinear quantum mechanical probabilities and rate constants for the Br + HCl(ν = 2, 3, 4) reaction using hyperspherical coordinates
✍ Jack A. Kaye; Aron Kuppermann 📂 Article 📅 1982 🏛 Elsevier Science 🌐 English ⚖ 449 KB

Calculations of quantum mechanical probabilities and rate constants for the collinear reaction Br + HC1 (o = 2, 3,4) BrH + C1, Br + HCI(o' < o) were performed using hyperspherical coordinates. Removal of vibrationaUy excited HC1 proceeds mainly by reaction to a nearly degenerate HBr state. Processes