𝔖 Bobbio Scriptorium
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Cohalogenation de cetones α, β-ethyleniques dans le THF

✍ Scribed by M. Bertrand; J-P Dulcere; J. Rodriquez; J-P Zahra


Publisher
Elsevier Science
Year
1983
Tongue
French
Weight
205 KB
Volume
24
Category
Article
ISSN
0040-4039

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✦ Synopsis


Chlorination of ~1, @-unsaturated ketones 2a-e at -80°C in THF gives _ rise exclusively

to cohaZogenation products 3a-e. The reaction is regiospecific.


📜 SIMILAR VOLUMES


Cetones α-fluoro α-ethyleniques: prepara
✍ Elias Elkik; Michèle Imbeaux-Oudotte 📂 Article 📅 1985 🏛 Elsevier Science 🌐 French ⚖ 190 KB

Reaction of dimethyl-suZfoxonium metkylide with non-kalogenated a-etkylenic-ketones is known to lead to cycZopropy2 derivatives. With ct-fluoro a-etkylenic-ketones this reaction furnishes fluoro-epoxides, by addition of a metkylene on carbonyl .