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Cofacial cyclopentadienes. Synthesis and reactions of 1,8-bis(cyclopentadienyl)naphthalene

✍ Scribed by Dana A. Gronbeck; Stephen A. Matchett; Myron Rosenblum


Book ID
104229300
Publisher
Elsevier Science
Year
1989
Tongue
French
Weight
181 KB
Volume
30
Category
Article
ISSN
0040-4039

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✦ Synopsis


unique bridged ferrocene IIrs is formed (22%).

An examination of the structure and chemistry of II an the use of 5 in the preparation of polymeric cofacial metallocenes is in progress.


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1,8-Bis(phosphino)naphthalenes: Synthesi
✍ Atilla KaraΓ§ar; Holger ThΓΆnnessen; Peter G. Jones; Rainer Bartsch; Reinhard Schm πŸ“‚ Article πŸ“… 1997 πŸ› John Wiley and Sons 🌐 English βš– 291 KB πŸ‘ 2 views

A series of 1,8-bis(phosphino)naphthalenes 2 was prepared by treating 1,8-dilithionaphthalene with the appropriate chloro-or bromophosphines RRЈPX; R, RЈ ‫ב‬ Me (for 2a), iPr (for 2c), Cy (for 2d), Ph (for 2f); R ‫ב‬ tBu, RЈ ‫ב‬ Ph (for 2e) (X ‫ב‬ Cl) and R, RЈ ‫ב‬ Et; X ‫ב‬ Br (for 2b). The resulti