Co(dmgH)2(NO2)[C6H3(CH3)2NH2]–Co(dmgH)2(NO2)(C6H3Cl2NH2) cocrystal
✍ Scribed by Calmuschi, Beatrice ;Kalf, Irmgard ;Kirch, Monika ;Thamer, Katja ;Englert, Ulli
- Publisher
- International Union of Crystallography
- Year
- 2002
- Tongue
- English
- Weight
- 275 KB
- Volume
- 58
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The structure of the (3,4-dimethylaniline)
, is reported. The complex crystallizes in space group P1 with statistical disorder between the chloro and methyl substituents.
Experimental
Co(dmgH) 2 (NO 2 )(OH 2 ) (Shkurpelo et al., 1979;Englert et al., 1999) was reacted separately with 3,4-dimethylaniline (L1) and 3,4-dichloroaniline (L2) to give complexes Co(dmgH) 2 (NO 2 )(L1) and Co(dmgH) 2 (NO 2 )(L2), respectively. The binary crystals formed from an equimolar solution of both complexes in acetone.
📜 SIMILAR VOLUMES
Durch den Schmelepunkt 141,5O war die Identitel derselben mit der Metanitrobenzogstiuree constaticl. Das vorliegende Nitroproduct hat sich daher a16 ein Metanitroorthotoluidin herausgestellt , dent die Stellung (4, 2, 3, CHs in i ) zugeschrieben werden mufs, da das andere Witxoorthotoluidin, dessen