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Co(dmgH)2(NO2)[C6H3(CH3)2NH2]–Co(dmgH)2(NO2)(C6H3Cl2NH2) cocrystal

✍ Scribed by Calmuschi, Beatrice ;Kalf, Irmgard ;Kirch, Monika ;Thamer, Katja ;Englert, Ulli


Publisher
International Union of Crystallography
Year
2002
Tongue
English
Weight
275 KB
Volume
58
Category
Article
ISSN
1600-5368

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✦ Synopsis


The structure of the (3,4-dimethylaniline)

, is reported. The complex crystallizes in space group P1 with statistical disorder between the chloro and methyl substituents.

Experimental

Co(dmgH) 2 (NO 2 )(OH 2 ) (Shkurpelo et al., 1979;Englert et al., 1999) was reacted separately with 3,4-dimethylaniline (L1) and 3,4-dichloroaniline (L2) to give complexes Co(dmgH) 2 (NO 2 )(L1) and Co(dmgH) 2 (NO 2 )(L2), respectively. The binary crystals formed from an equimolar solution of both complexes in acetone.


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