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Cocrystals of 2,4-Diamino-6-phenyl-1,3,5-triazine with Dicarboxylic Acids

✍ Scribed by Bigyan R. Jali, Jubaraj B. Baruah

Book ID
120689067
Publisher
Springer
Year
2013
Tongue
English
Weight
489 KB
Volume
43
Category
Article
ISSN
1572-8854

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In the title cocrystal, C~9~H~9~N~5~Β·C~6~H~8~O~2~, the asymmetric unit contains one 2,4-diamino-6-phenyl-1,3,5-triazine molecule and a sorbic acid molecule. The triazine molecules are base-paired [with a graph set of __R__ ~2~ ^2^(8)] on either side __via__ Nβ€”H...N hydrogen bonds, forming a supramol

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The title compound, C 8 H 2 Cl 4 O 4 , was synthesized by the reaction of 2,3,5,6-tetrachlorobenzene-1,4-dicarbonitrile and sulfuric acid. The molecule is located across an inversion center. The carboxyl group is tilted with respect to the benzene ring by an angle of 72.42 (7) . Intermolecular O-HÁ