Cobalt(II) complexes reversibly uptaking nitric oxide in aqueous solution
✍ Scribed by B. Jeżowska-Trzebiatowska; K. Gerega; A. Vogt
- Publisher
- Elsevier Science
- Year
- 1978
- Tongue
- English
- Weight
- 285 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0020-1693
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We report here a photochemical study of cis-[RuCl(bpy) 2 (NO)](PF 6 ) 2 in aqueous solution with flash-photolysis at 355 nm light. The spectroelectrochemistry and pH effect were also determined. NO was measured in situ with an NO sensor. Light intensities were determined by ferrioxalate actinometry.
The pressure-jump method has been used to determine the rate constants for the formation and dissociation of nickel(I1) and cobalt(I1) complexes with cinchomeronate in aqueous solution at zero ionic strength. The forward and reverse rate constants obtained are k, = 2.27 x lo6 M-' s-' and k, = 3.81 x