1H NMR of paramagnetic cobalt(II) and nickel(II) complexes of dialkylsulfoxides in aqueous solution
β Scribed by Sh. A. Markaryan
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 1989
- Tongue
- English
- Weight
- 515 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0022-4766
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π SIMILAR VOLUMES
The pressure-jump method has been used to determine the rate constants for the formation and dissociation of nickel(I1) and cobalt(I1) complexes with cinchomeronate in aqueous solution at zero ionic strength. The forward and reverse rate constants obtained are k, = 2.27 x lo6 M-' s-' and k, = 3.81 x
## Abstract The first row transition metal ions Mn^2+^, Co^2+^, and Ni^2+^ have been studied by classical umbrella sampling molecular dynamics simulations. The water exchange mechanisms, estimates of reaction rates, as well as structural changes during the activation process are discussed. Mn^2+^ w