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Cobalt(diamine)-Catalyzed Cross-Coupling Reaction of Alkyl Halides with Arylmagnesium Reagents: Stereoselective Constructions of Arylated Asymmetric Carbons and Application to Total Synthesis of AH13205.

✍ Scribed by Hirohisa Ohmiya; Hideki Yorimitsu; Koichiro Oshima

Publisher
John Wiley and Sons
Year
2006
Weight
28 KB
Volume
37
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

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πŸ“œ SIMILAR VOLUMES

Cobalt-Catalyzed Cross-Coupling Reaction
Cobalt-Catalyzed Cross-Coupling Reactions of Alkyl Halides with Allylic and Benzylic Grignard Reagents and Their Application to Tandem Radical Cyclization/Cross-Coupling Reactions
✍ Hirohisa Ohmiya; Takashi Tsuji; Hideki Yorimitsu; Koichiro Oshima πŸ“‚ Article πŸ“… 2004 πŸ› John Wiley and Sons 🌐 English βš– 317 KB πŸ‘ 2 views

## Abstract Details of cobalt‐catalyzed cross‐coupling reactions of alkyl halides with allylic Grignard reagents are disclosed. A combination of cobalt(II) chloride and 1,2‐bis(diphenylphosphino)ethane (DPPE) or 1,3‐bis(diphenylphosphino)propane (DPPP) is suitable as a precatalyst and allows second