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Cobalt-Catalyzed Cross-Coupling Reactions of Alkyl Halides with Aryl Grignard Reagents and Their Application to Sequential Radical Cyclization/Cross-Coupling Reactions.

✍ Scribed by Hirohisa Ohmiya; Katsuyu Wakabayashi; Hideki Yorimitsu; Koichiro Oshima

Publisher
John Wiley and Sons
Year
2006
Weight
34 KB
Volume
37
Category
Article
ISSN
0931-7597

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Cobalt-Catalyzed Cross-Coupling Reaction
Cobalt-Catalyzed Cross-Coupling Reactions of Alkyl Halides with Allylic and Benzylic Grignard Reagents and Their Application to Tandem Radical Cyclization/Cross-Coupling Reactions
✍ Hirohisa Ohmiya; Takashi Tsuji; Hideki Yorimitsu; Koichiro Oshima πŸ“‚ Article πŸ“… 2004 πŸ› John Wiley and Sons 🌐 English βš– 317 KB πŸ‘ 2 views

## Abstract Details of cobalt‐catalyzed cross‐coupling reactions of alkyl halides with allylic Grignard reagents are disclosed. A combination of cobalt(II) chloride and 1,2‐bis(diphenylphosphino)ethane (DPPE) or 1,3‐bis(diphenylphosphino)propane (DPPP) is suitable as a precatalyst and allows second