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Cobalt hydrogen selenite chloride dihydrate, Co(HSeO3)Cl·2H2O

✍ Scribed by Johnston, Magnus G. ;Harrison, William T. A.

Publisher
International Union of Crystallography
Year
2003
Tongue
English
Weight
382 KB
Volume
59
Category
Article
ISSN
1600-5368

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✦ Synopsis

Cobalt hydrogen selenite chloride dihydrate, Co(HSeO 3 )ClÁ-2H 2 O, is built up from a network of trans CoO 4 Cl 2 octahedra, cis Co(H 2 O) 4 Cl 2 octahedra and HSeO 3 pyramids. These units [d av (CoÐO) = 2.075 (2) A Ê , d av (CoÐCl) = 2.5370 (6) A Ê and d av (SeÐO) = 1.703 (2) A Ê ] share vertices by way of CoÐOÐ Se and CoÐClÐCo bonds to produce a three-dimensional structure. Co of the trans octahedron occupies an inversion centre; Co of the cis octahedron and two attached water O atoms lie on a mirror plane. The hydrogen-bonding scheme has been elucidated and involves OÐHÁ Á ÁO and OÐHÁ Á ÁCl interactions. The title compound is isostructural with Cu(HSeO 3 )ClÁ2H 2 O, although the metal polyhedra are distinctly different in the two phases.

📜 SIMILAR VOLUMES

Syntheses and Structures of Two Selenite
Syntheses and Structures of Two Selenite Chloride Hydrates: Co(HSeO3)Cl · 3 H2O and Cu(HSeO3)Cl · 2 H2O
✍ Magnus G. Johnston; William T. A. Harrison 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 German ⚖ 132 KB 👁 2 views

The first selenite chloride hydrates, Co(HSeO 3 )-Cl ´3 H 2 O and Cu(HSeO 3 )Cl ´2 H 2 O, have been prepared from solution and characterised by single-crystal X-ray diffraction. The cobalt phase adopts an unusual ªone-dimensionalº structure built up from vertex-sharing pyramidal [HSeO 3 ] 2± , and o

Crystal Structure, Thermal Behavior, and
Crystal Structure, Thermal Behavior, and Infrared Absorption Spectrum of Cobalt(II) Hydrogen Selenite Dihydrate Co(HSeO3)2 · 2H2O
✍ Zdeněk Mička; Ivan Němec; Pavel Vojtı́šek; Jan Ondráček; Jorma Hölsä 📂 Article 📅 1994 🏛 Elsevier Science 🌐 English ⚖ 227 KB

The crystal structure, thermoanalytical properties, and infrared absorption spectra of \(\mathrm{Co}\left(\mathrm{HSeO}_{3}\right)_{2} \cdot 2 \mathrm{H}_{2} \mathrm{O}\) are given. The crystals of the substance are monoclinic, with space group \(P 21 / n, a=\) \(7.1357(6) \AA, b=6.8759(6) \AA, c=8.