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Cobalt-Catalyzed Tandem Radical Cyclization and Cross-Coupling Reaction: Its Application to Benzyl-Substituted Heterocycles

✍ Scribed by Wakabayashi, Katsuyu; Yorimitsu, Hideki; Oshima, Koichiro


Book ID
120287153
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
35 KB
Volume
123
Category
Article
ISSN
0002-7863

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## Abstract Details of cobalt‐catalyzed cross‐coupling reactions of alkyl halides with allylic Grignard reagents are disclosed. A combination of cobalt(II) chloride and 1,2‐bis(diphenylphosphino)ethane (DPPE) or 1,3‐bis(diphenylphosphino)propane (DPPP) is suitable as a precatalyst and allows second