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Cobalt catalyzed oxidation of benzoin

✍ Scribed by Shigeru Tsuruya; Toshio Masuoka; Mitsuo Masai

Publisher
Elsevier Science
Year
1980
Weight
764 KB
Volume
10
Category
Article
ISSN
0304-5102

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Chiral Cobalt-Catalyzed Enantiomer-Diffe
Chiral Cobalt-Catalyzed Enantiomer-Differentiating Oxidation of Racemic Benzoins by Using Molecular Oxygen as Stoichiometric Oxidant
✍ Santosh Kumarβ€…Alamsetti; Pandi Muthupandi; Govindasamy Sekar πŸ“‚ Article πŸ“… 2009 πŸ› John Wiley and Sons 🌐 English βš– 196 KB

## Abstract **An efficient enantioselective** oxidative reaction catalyzed by a chiral cobalt complex has been developed by using molecular oxygen as the stoichiometric oxidant (see scheme). The very mild reaction conditions of the catalytic system provide access to a wide range of benzoins (α‐hydr