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Cobalt-catalyzed arylation of aldimines via directed C–H bond functionalization: addition of 2-arylpyridines and self-coupling of aromatic aldimines

✍ Scribed by Gao, Ke; Yoshikai, Naohiko

Book ID
115454152
Publisher
Royal Society of Chemistry
Year
2012
Tongue
English
Weight
682 KB
Volume
48
Category
Article
ISSN
1359-7345

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Rhodium-catalyzed ortho-alkylation of ar
Rhodium-catalyzed ortho-alkylation of aromatic aldimines and ketimines via CH bond activation
✍ Yeong-Gweon Lim; Jong-Soo Han; Seung-Sun Yang; Jong Han Chun 📂 Article 📅 2001 🏛 Elsevier Science 🌐 French ⚖ 108 KB

The aldimines reacted with alkenes under a rhodium catalytic system, Rh[(coe) 2 Cl] 2 and Cy 3 P, to give mainly the double alkylated products with moderate to high yields. On the other hand, the ketimine 9 gave the mono alkylated product predominantly.