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Cobalt-catalyzed [4 + 2 + 2] cycloadditions of bicyclo[2.2.2]octadienes

✍ Scribed by Rattana Kiattansakul; John K. Snyder

Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
263 KB
Volume
40
Category
Article
ISSN
0040-4039

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## Abstract The behaviour of bicyclo [2.2.2]octa‐2,5‐diene (1) towards perbenzoic acid, 2,4 dinitrophenylsulfenyl chloride and ozone has been studied. In no instance was the formation of a homotricyclene derivative by homoconjugative addition observed. However, the primary formation of homoallylic